Electrodeposition of PbO and its in situ conversion to CH3NH3PbI3 for mesoscopic perovskite solar cells.

نویسندگان

  • Xue-Ping Cui
  • Ke-Jian Jiang
  • Jin-Hua Huang
  • Xue-Qin Zhou
  • Mei-Ju Su
  • Shao-Gang Li
  • Qian-Qian Zhang
  • Lian-Min Yang
  • Yan-Lin Song
چکیده

The perovskite CH3NH3PbI3 was prepared on a mesoscopic TiO2 film, starting from electrodepositing PbO, to iodination to PbI2, and then interdiffusion reaction with CH3NH3I. The as-prepared film was used as a light absorber for the perovskite solar cells, exhibiting a high PCE of 12.5% under standard AM 1.5 conditions.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Direct Conversion of CH3NH3PbI3 from Electrodeposited PbO for Highly Efficient Planar Perovskite Solar Cells

Organic-inorganic hybrid perovskite materials have recently been identified as a promising light absorber for solar cells. In the efficient solar cells, the perovskite active layer has generally been fabricated by either vapor deposition or two-step sequential deposition process. Herein, electrochemically deposited PbO film is in situ converted into CH3NH3PbI3 through solid-state reaction with ...

متن کامل

افزایش پایداری سلول‌های خورشیدی با استفاده از لایه‌های جاذب پروسکایتی CH3NH3PbI3 آلاییده با برم

The CH3NH3PbI3 is one of the most widely used and famous lead halide perovskite absorber layer for using in perovskite solar cells. One of the ways to deal with the instability problem of this perovskite structure in environmental condition is bromide doping in this composition. In this work, the structural and optical properties of the bromide doped CH3NH3PbI3 absorber layers were studied as w...

متن کامل

Full Printable Processed Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells with Carbon Counter Electrode

A mesoscopic methylammonium lead iodide (CH₃NH₃PbI₃) perovskite/TiO₂ heterojunction solar cell is developed with low-cost carbon counter electrode (CE) and full printable process. With carbon black/spheroidal graphite CE, this mesoscopic heterojunction solar cell presents high stability and power conversion efficiency of 6.64%, which is higher than that of the flaky graphite based device and co...

متن کامل

Flexible, low-temperature, solution processed ZnO-based perovskite solid state solar cells.

A ZnO compact layer formed by electrodeposition and ZnO nanorods grown by chemical bath deposition (CBD) allow the processing of low-temperature, solution based and flexible solid state perovskite CH3NH3PbI3 solar cells. Conversion efficiencies of 8.90% were achieved on rigid substrates while the flexible ones yielded 2.62%.

متن کامل

Fully printable mesoscopic perovskite solar cells with organic silane self-assembled monolayer.

By the introduction of an organic silane self-assembled monolayer, an interface-engineering approach is demonstrated for hole-conductor-free, fully printable mesoscopic perovskite solar cells based on a carbon counter electrode. The self-assembled silane monolayer is incorporated between the TiO2 and CH3NH3PbI3, resulting in optimized interface band alignments and enhanced charge lifetime. The ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Chemical communications

دوره 51 8  شماره 

صفحات  -

تاریخ انتشار 2015